Dioxidobis(2-oxo-1,2-dihydropyridin-3-olato)molybdenum(VI)
نویسندگان
چکیده
In the title compound, [Mo(C(5)H(4)NO(2))(2)O(2)], the Mo(VI) atom exhibits a distorted octa-hedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other. The crystal structure contains inter-molecular N-H⋯O hydrogen bonds, C-H⋯O contacts and face-to-face π-π stacking inter-actions with an inter-planar separation of 3.25 (1) Å.
منابع مشابه
Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008